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Statistical modeling of radiolytic (

G. S. Muthu Iswarya, B. Nirkayani, A. Kavithakani, V. C. Padmanaban

《环境科学与工程前沿(英文)》 2019年 第13卷 第3期 doi: 10.1007/s11783-019-1126-3

摘要:

Linear, interactive and quadratic effects of process parameters were studied.

Degradation of Ofloxacin (Ofx) was related with G value of irradiation process.

The synergistic effect of H2O2 on lower dose of g-irradiation was established.

The process follows pseudo first order with dose constant (d = 0.232 kGy1).

关键词: Ofloxacin     Gamma irradiation     Face centered central composite design     Reaction kinetics     Gas Chromatography-Mass spectrum    

Degradation of refractory organics in concentrated leachate by the Fenton process: Central compositedesign for process optimization

Senem Yazici Guvenc, Gamze Varank

《环境科学与工程前沿(英文)》 2021年 第15卷 第1期 doi: 10.1007/s11783-020-1294-1

摘要: Abstract • 90% total COD, 95.3% inert COD and 97.2% UV254 were removed. • High R2 values (over 95%) for all responses were obtained with CCD. • Operational cost was calculated to be 0.238 €/g CODremoved for total COD removal. • Fenton oxidation was highly-efficient method for inert COD removal. • BOD5/COD ratio of leachate concentrate raised from 0.04 to 0.4. The primary aim of this study is inert COD removal from leachate nanofiltration concentrate because of its high concentration of resistant organic pollutants. Within this framework, this study focuses on the treatability of leachate nanofiltration concentrate through Fenton oxidation and optimization of process parameters to reach the maximum pollutant removal by using response surface methodology (RSM). Initial pH, Fe2+ concentration, H2O2/Fe2+ molar ratio and oxidation time are selected as the independent variables, whereas total COD, color, inert COD and UV254 removal are selected as the responses. According to the ANOVA results, the R2 values of all responses are found to be over 95%. Under the optimum conditions determined by the model (pH: 3.99, Fe2+: 150 mmol/L, H2O2/Fe2+: 3.27 and oxidation time: 84.8 min), the maximum COD removal efficiency is determined as 91.4% by the model. The color, inert COD and UV254 removal efficiencies are determined to be 99.9%, 97.2% and 99.5%, respectively, by the model, whereas the total COD, color, inert COD and UV254 removal efficiencies are found respectively to be 90%, 96.5%, 95.3% and 97.2%, experimentally under the optimum operating conditions. The Fenton process improves the biodegradability of the leachate NF concentrate, increasing the BOD5/COD ratio from the value of 0.04 to the value of 0.4. The operational cost of the process is calculated to be 0.238 €/g CODremoved. The results indicate that the Fenton oxidation process is an efficient and economical technology in improvement of the biological degradability of leachate nanofiltration concentrate and in removal of resistant organic pollutants.

关键词: Concentrated leachate     Fenton oxidation     Central composite design     Biodegradability     Inert COD    

Development of a multi-component drug from turmeric using central composite design

Xiaohang ZHANG,Shengnan HAN,Yan LI,Jianlan JIANG

《化学科学与工程前沿(英文)》 2014年 第8卷 第3期   页码 362-368 doi: 10.1007/s11705-014-1439-5

摘要: A methodology to develop multi-component drugs based on traditional Chinese medicines has been developed using central composite design. Several active components from the traditional Chinese medicine turmeric were chosen for use in a multi-component antitumor drug. Response surface methodology based on a central composite design was applied to determine the quantitative composition-activity relationships in order to optimize the amount of each component in the drug. An MTT (3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide) assay was used to measure the pharmacological activity as the response value. The experimental antitumor activity of the optimum combination was 92.85% in the MTT assay and superior to the activities of each single component. These results demonstrate that response surface methodology based on a central composite design is suitable for the design of multi-component drugs.

关键词: multi-component drug development     central composite design     turmeric     curcuminoids    

Modeling of ion conductivity in Nafion membranes

YANG Zhen, PENG Xiaofeng, WANG Buxuan, DUAN Yuanyuan, LEE Duujong

《能源前沿(英文)》 2007年 第1卷 第1期   页码 58-66 doi: 10.1007/s11708-007-0005-y

摘要: A theoretical investigation was conducted to describe the ion transport behavior in a Nafion Membrane of proton exchange membrane fuel cells (PEMFC). By analyzing the surface energy configuration of the ionic clusters in a Nafion membrane, an equivalent field intensity, , was introduced to facilitate the analysis of surface resistance against ion conduction in the central region of clusters. An expression was derived for ionic conductivity incorporating the influence of surface resistance. A face-centered cubic (FCC) lattice model for a spatial cluster distribution was used to modify the effect of water content on ionic conductivity in the polymeric matrix, i.e., the regions between clusters. Compared with the available empirical correlations, the new expression showed much better agreement with the available experimental results, which indicates the rationality to consider the structural influence on ion conduction in water-swollen Nafion membranes.

关键词: face-centered     polymeric     theoretical investigation     conduction     equivalent    

Nano-copper ions assembled cellulose-based composite with antibacterial activity for biodegradable personal

《化学科学与工程前沿(英文)》 2023年 第17卷 第10期   页码 1544-1554 doi: 10.1007/s11705-022-2288-2

摘要: The current SARS-CoV-2 pandemic has resulted in the widespread use of personal protective equipment, particularly face masks. However, the use of commercial disposable face masks puts great pressure on the environment. In this study, nano-copper ions assembled cotton fabric used in face masks to impart antibacterial activity has been discussed. To produce the nanocomposite, the cotton fabric was modified by sodium chloroacetate after its mercerization, and assembled with bactericidal nano-copper ions (about 10.61 mg·g–1) through electrostatic adsorption. It demonstrated excellent antibacterial activity against Staphylococcus aureus and Escherichia coli because the gaps between fibers in the cotton fabric allow the nano-copper ions to be fully released. Moreover, the antibacterial efficiency was maintained even after 50 washing cycles. Furthermore, the face mask constructed with this novel nanocomposite upper layer exhibited a high particle filtration efficiency (96.08% ± 0.91%) without compromising the air permeability (28.9 min·L–1). This green, economical, facile, and scalable process of depositing nano-copper ions onto modified cotton fibric has great potential to reduce disease transmission, resource consumption, and environmental impact of waste, while also expanding the range of protective fabrics.

关键词: cellulose-based     nanocomposite     biodegradable antibacterial fabric     nano-copper ions     face masks    

高混凝土面板堆石坝设计新理念

郦能惠

《中国工程科学》 2011年 第13卷 第3期   页码 12-18

摘要:

在分析混凝土面板堆石坝40多年经验设计及其不完全性的基础上,提出了高混凝土面板堆石坝设计新理念,即针对坝址的地形地质条件与料源情况,进行稳定安全设计、渗流安全设计和变形安全设计,阐述了稳定、渗流、变形安全设计的原则和要点,强调了变形协调原则和理论指导设计的重要性。

关键词: 混凝土面板堆石坝     设计新理念     稳定安全     渗流安全     变形安全    

Removal of malachite green from aqueous solution by sorption on hydrilla verticillata biomass using response surface methodology

R. RAJESHKANNAN, N. RAJAMOHAN, M. RAJASIMMAN

《化学科学与工程前沿(英文)》 2009年 第3卷 第2期   页码 146-154 doi: 10.1007/s11705-009-0007-x

摘要: In the present study, the effect of adsorbent dose, pH, temperature, initial dye concentration and contact time on malachite green removal from an aqueous medium using hydrilla verticillata biomass has been investigated. The central composite face-centered experimental design (CFCD) in response surface methodology (RSM) was used for designing the experiments as well as for full response surface estimation. The optimum conditions for maximum removal of malachite green from an aqueous solution of 75.52 mg/L were as follows: adsorbent dose (11.14 g/L), pH (8.4), temperature (48.4°C) and contact time (194.5 min). This was evidenced by the higher value of coefficient of determination ( =0.9158).

关键词: response surface methodology     hydrilla verticillata     malachite green     adsorption     central composite design    

Trial design of arch bridge of composite box section with steel web-concrete flange

Jiangang WEI, Qingwei HUANG, Baochun CHEN,

《结构与土木工程前沿(英文)》 2010年 第4卷 第3期   页码 370-375 doi: 10.1007/s11709-010-0073-7

摘要: The concrete arch bridge is a natural and appropriate structural solution, aesthetically pleasing and easily integrated into the environment, especially in mountainous and island areas. However, construction difficulty and cost will increase with heavy self-weight when the span enlarges. A potential solution is to use a composite box arch ring with steel web-concrete flange. Taking Wanzhou Yangtze River Bridge (the longest concrete arch bridge in the world with a main span of 420 m) as a prototype, trial designs of a composite box arch with steel webs (including corrugated steel webs and plain steel webs) and concrete flanges were carried out. Comparison of quantities and structural behaviors of the prototype concrete arch with the two trial designed composite arch was presented. It is shown that the self-weight of the composite arch can reduce about 28% and the structures can meet the design requirements, therefore it is possible to use the two composite arches in long span arch bridges.

关键词: steel webs     concrete     box arch     trial design     structural behaviors     finite element method    

Design of composite flywheel rotor

BAI Yue, GAO Qingjia, LI Haiwen, WU Yihui, XUAN Ming

《机械工程前沿(英文)》 2008年 第3卷 第3期   页码 288-292 doi: 10.1007/s11465-008-0045-y

摘要: A design method for a flywheel rotor composed of a composite rim and a metal hub is proposed by studying the connection between the rotor and the driving machine. The influence of some factors such as the rotor material, configuration, connection, and fracture techniques on energy density is analyzed. The results show that the ratio of the inner radius to outer radius of the rim is the key factor, and is determined by the rim material. Optimizing the hub can further efficiently improve energy density. The composite flywheel rotor is produced and its rotation stress has been tested at the speed of 20 krpm. The emulation results are consistent with testing results, which proves that the introduced design method is useful.

关键词: introduced     useful     density     composite     driving machine    

Analysis and design of steel-concrete composite sandwich systems subjected to extreme loads

Kazi Md Abu SOHEL, Jat Yuen Richard LIEW, Min Hong ZHANG

《结构与土木工程前沿(英文)》 2011年 第5卷 第3期   页码 278-293 doi: 10.1007/s11709-011-0120-z

摘要: This paper presents the design guide based on analytical, numerical and experimental investigation of Steel-concrete-steel (SCS) sandwich structural members comprising a lightweight concrete core with density ranged from 1300 to 1445 kg/m subjected to static, impact and blast loads. The performance of lightweight sandwich members is also compared with similar members with normal weight concrete core and ultra high strength concrete core ( = 180 MPa). Novel J-hook shear connectors were invented to prevent the separation of face plates from the concrete core under extreme loads and their uses are not restricted by the concrete core thickness. Flexural and punching are the primary modes of failure under static point load. Impact test results show that the SCS sandwich panels with the J-hook connectors are capable of resisting impact load with less damage in comparison than equivalent stiffened steel plate panels. Blast tests with 100 kg TNT were performed on SCS sandwich specimens to investigate the key parameters that affect the blast resistance of SCS sandwich structure. Plastic yield line method is proposed to predict the plastic capacity and post peak large deflection of the sandwich plates. Finally, an energy balanced model is developed to analyze the global behavior of SCS sandwich panels subjected to dynamic load.

关键词: blast load     composite structure     impact load     lightweight concrete     sandwich plate     J-hook connector    

Design concepts of an aircraft wing: composite and morphing airfoil with auxetic structures

P R BUDARAPU,Sudhir Sastry Y B,R NATARAJAN

《结构与土木工程前沿(英文)》 2016年 第10卷 第4期   页码 394-408 doi: 10.1007/s11709-016-0352-z

摘要: This paper is categorized into two parts. (1) A frame work to design the aircraft wing structure and (2) analysis of a morphing airfoil with auxetic structure. The developed design frame work in the first part is used to arrive at the sizes of the various components of an aircraft wing structure. The strength based design is adopted, where the design loads are extracted from the aerodynamic loads. The aerodynamic loads acting on a wing structure are converted to equivalent distributed loads, which are further converted point loads to arrive at the shear forces, bending and twisting moments along the wing span. Based on the estimated shear forces, bending and twisting moments, the strength based design is employed to estimate the sizes of various sections of a composite wing structure. A three dimensional numerical model of the composite wing structure has been developed and analyzed for the extreme load conditions. Glass fiber reinforced plastic material is used in the numerical analysis. The estimated natural frequencies are observed to be in the acceptable limits. Furthermore, the discussed design principles in the first part are extended to the design of a morphing airfoil with auxetic structure. The advantages of the morphing airfoil with auxetic structure are (i) larger displacement with limited straining of the components and (ii) unique deformation characteristics, which produce a theoretical in-plane Poisson’s ratio of −1. Aluminum Alloy AL6061-T651 is considered in the design of all the structural elements. The compliance characteristics of the airfoil are investigated through a numerical model. The numerical results are observed to be in close agreement with the experimental results in the literature.

关键词: wing design     aerodynamic loads     morphing airfoil     auxetic structures     negative Poisson’s ratio    

Seismic performance of fabricated continuous girder bridge with grouting sleeve-prestressed tendon composite

《结构与土木工程前沿(英文)》   页码 827-854 doi: 10.1007/s11709-023-0954-1

摘要: The seismic performance of a fully fabricated bridge is a key factor limiting its application. In this study, a fiber element model of a fabricated concrete pier with grouting sleeve-prestressed tendon composite connections was built and verified. A numerical analysis of three types of continuous girder bridges was conducted with different piers: a cast-in-place reinforced concrete pier, a grouting sleeve-fabricated pier, and a grouting sleeve-prestressed tendon composite fabricated pier. Furthermore, the seismic performance of the composite fabricated pier was investigated. The results show that the OpenSees fiber element model can successfully simulate the hysteresis behavior and failure mode of the grouted sleeve-fabricated pier. Under traditional non-near-fault ground motions, the pier top displacements of the grouting sleeve-fabricated pier and the composite fabricated pier were less than those of the cast-in-place reinforced concrete pier. The composite fabricated pier had a good self-centering capability. In addition, the plastic hinge zones of the grouting sleeve-fabricated pier and the composite fabricated pier shifted to the joint seam and upper edge of the grouting sleeve, respectively. The composite fabricated pier with optimal design parameters has good seismic performance and can be applied in high-intensity seismic areas; however, the influence of pile-soil interaction on its seismic performance should not be ignored.

关键词: seismic performance     continuous girder bridge     grouting sleeve-prestressed tendon composite connections     grouted sleeve connection     design parameters    

多相复合陶瓷刀具材料的设计与制备

许崇海,艾兴

《中国工程科学》 2001年 第3卷 第3期   页码 71-74

摘要:

陶瓷材料的多相复合与计算机辅助设计是21世纪先进陶瓷材料的重要发展趋势。文章采用理论与实验相结合的方法,建立了多相复合陶瓷刀具材料力学性能与材料组分之间关系的数学模型,采用计算机辅助优 化设计技术求得材料的最优组分。在此基础上,利用热压技术制得一种Al23-SiC-(W,Ti) C多相复合陶瓷刀具材料,该材料具有良好的综合力学性能。

关键词: 陶瓷刀具材料     多相复合     材料设计     模型     力学性能    

Effect of cutterhead configuration on tunnel face stability during shield machine maintenance outages

《结构与土木工程前沿(英文)》 2023年 第17卷 第4期   页码 522-532 doi: 10.1007/s11709-023-0930-9

摘要: Owing to long-distance advancement or obstacles, shield tunneling machines are typically shut down for maintenance. Engineering safety during maintenance outages is determined by the stability of the tunnel face. Pressure maintenance openings are typically used under complicated hydrogeological conditions. The tunnel face is supported by a medium at the bottom of the excavation chamber and compressed air at the top. Owing to the high risk of face failure, the necessity of support pressure when cutterhead support is implemented and a method for determining the value of compressed air pressure using different support ratios must to be determined. In this study, a non-fully chamber supported rotational failure model considering cutterhead support is developed based on the upper-bound theorem of limit analysis. Numerical simulation is conducted to verify the accuracy of the proposed model. The results indicate that appropriately increasing the specific gravity of the supporting medium can reduce the risk of collapse. The required compressed air pressure increases significantly as the support ratio decreases. Disregarding the supporting effect of the cutterhead will result in a tunnel face with underestimated stability. To satisfy the requirement of chamber openings at atmospheric pressure, the stratum reinforcement strength and range at the shield end are provided based on different cutterhead aperture ratios.

关键词: tunnel face stability     cutterhead configuration     aperture ratio     pressure gradient     support ratio    

Method for solving the nonlinear inverse problem in gas face seal diagnosis based on surrogate models

《机械工程前沿(英文)》 2022年 第17卷 第3期 doi: 10.1007/s11465-022-0689-z

摘要: Physical models carry quantitative and explainable expert knowledge. However, they have not been introduced into gas face seal diagnosis tasks because of the unacceptable computational cost of inferring the input fault parameters for the observed output or solving the inverse problem of the physical model. The presented work develops a surrogate-model-assisted method for solving the nonlinear inverse problem in limited physical model evaluations. The method prepares a small initial database on sites generated with a Latin hypercube design and then performs an iterative routine that benefits from the rapidity of the surrogate models and the reliability of the physical model. The method is validated on simulated and experimental cases. Results demonstrate that the method can effectively identify the parameters that induce the abnormal signal output with limited physical model evaluations. The presented work provides a quantitative, explainable, and feasible approach for identifying the cause of gas face seal contact. It is also applicable to mechanical devices that face similar difficulties.

关键词: surrogate model     gas face seal     fault diagnosis     nonlinear dynamics     tribology    

标题 作者 时间 类型 操作

Statistical modeling of radiolytic (

G. S. Muthu Iswarya, B. Nirkayani, A. Kavithakani, V. C. Padmanaban

期刊论文

Degradation of refractory organics in concentrated leachate by the Fenton process: Central compositedesign for process optimization

Senem Yazici Guvenc, Gamze Varank

期刊论文

Development of a multi-component drug from turmeric using central composite design

Xiaohang ZHANG,Shengnan HAN,Yan LI,Jianlan JIANG

期刊论文

Modeling of ion conductivity in Nafion membranes

YANG Zhen, PENG Xiaofeng, WANG Buxuan, DUAN Yuanyuan, LEE Duujong

期刊论文

Nano-copper ions assembled cellulose-based composite with antibacterial activity for biodegradable personal

期刊论文

高混凝土面板堆石坝设计新理念

郦能惠

期刊论文

Removal of malachite green from aqueous solution by sorption on hydrilla verticillata biomass using response surface methodology

R. RAJESHKANNAN, N. RAJAMOHAN, M. RAJASIMMAN

期刊论文

Trial design of arch bridge of composite box section with steel web-concrete flange

Jiangang WEI, Qingwei HUANG, Baochun CHEN,

期刊论文

Design of composite flywheel rotor

BAI Yue, GAO Qingjia, LI Haiwen, WU Yihui, XUAN Ming

期刊论文

Analysis and design of steel-concrete composite sandwich systems subjected to extreme loads

Kazi Md Abu SOHEL, Jat Yuen Richard LIEW, Min Hong ZHANG

期刊论文

Design concepts of an aircraft wing: composite and morphing airfoil with auxetic structures

P R BUDARAPU,Sudhir Sastry Y B,R NATARAJAN

期刊论文

Seismic performance of fabricated continuous girder bridge with grouting sleeve-prestressed tendon composite

期刊论文

多相复合陶瓷刀具材料的设计与制备

许崇海,艾兴

期刊论文

Effect of cutterhead configuration on tunnel face stability during shield machine maintenance outages

期刊论文

Method for solving the nonlinear inverse problem in gas face seal diagnosis based on surrogate models

期刊论文